The isotopic composition of volatiles in the unique Bench Crater carbonaceous chondrite impactor found in the Apollo 12 regolith

Abstract

Projectiles striking the Moon have modified its crust and delivered volatile elements to its interior and surface. Direct evidence of impactor origins is recorded by the rare occurrence of sub-cm sized meteorite fragments identified in Apollo samples and lunar meteorites. The Bench Crater meteorite is a millimetre-sized carbonaceous chondrite collected in regolith on the rim of Bench impact crater at the Apollo 12 landing site. Transmission electron microscopy has previously shown that Bench Crater contains abundant hydrated silicates, establishing the survivability of hydrated material impacting the lunar surface. To provide further information on the volatile inventory of the Bench Crater meteorite, we report here the isotope compositions of hydrogen, nitrogen, carbon and oxygen. This is the first direct isotopic analysis of meteoritic material delivered to the lunar surface and provides context for volatile and organic element signatures in lunar regolith samples, and the survivability of volatile material delivered to planetary surfaces during impact bombardment.